Chemical Resistance - Caps and Plugs

Hazardous chemicals in brightly coloured labelled containers

One purpose of caps and plugs is to protect your application from the damaging effects of chemicals. Beware when you make your choice. Not all caps and plugs are equal in providing the protection you need, which is why your choice of material is critical. In this article we cover: 

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The chemical resistance of caps and plugs

Chemicals can come into contact with any application. It doesn’t have to be part of the manufacturing process. Here’s a look at the plastics chemical resistance of the materials that caps and plugs are made of. We’ll start with plastics, according to the British Plastics Federation:

Chemical Resistance

LDPE

HDPE

Nylon

EVA

PP

PVC

TPE

Dilute Acids

Excellent

Excellent

Poor

Excellent

Very good

Very good

Excellent

Dilute Alkalis

Excellent

Excellent

Moderate

Excellent

Very good

Very good

Excellent

Oils and Grease

Moderate (Variable)

Moderate (Variable)

Excellent

Good

Moderate (Variable)

Good (Variable)

Excellent

Aliphatic Hydrocarbons

Poor

Poor

Excellent

Excellent

Poor

Very good

Excellent

Aromatic Hydrocarbons

Poor

Poor

Excellent

Poor

Poor

Poor

Poor

Halogenated Hydrocarbons

Poor

Poor

Good (Variable)

Poor

Poor

Moderate (Variable)

Poor

Alcohols

Excellent

Excellent

Good (Variable)

Excellent

Very good

Good (Variable)

Excellent

 

Plastics at a glance:

  • Low Density Polyethylene (LDPE): Can withstand the cold, specifically temperatures down to -50ºC before it becomes brittle.
  • High-density polyethylene (HDPE): Low permeability to gases and moisture makes it a good choice for protecting NPT thread ports from dirt and other contaminants.
  • Nylon: Most nylons are semi-crystalline. Usually very tough materials, nylons offer good thermal and chemical resistance.
  • Ethylene Vinyl Acetate (EVA): Has low-temperature toughness, stress-crack resistance, and hot-melt adhesive waterproof properties. It’s also resistance to UV radiation.
  • Polypropylene (PP): An extremely versatile material, tough with good chemical and fatigue resistance.
  • Polyvinyl Chloride (PVC): Most popular polymer in the world, PVC is durable and long lasting.
  • Thermoplastic elastomers (TPE): Soft and resistant to UV rays. Some manufacturers class TPE as a rubber.

Rubbers

The following table gives an overview on the chemical resistance of rubbers.

Chemical Resistance

EDPM

Nitrile

Silicone

TPR

Resistance to weather and UV rays

Excellent

Poor

Poor

Excellent

Water resistance

Excellent

Good

Excellent

Excellent

Chemical resistance

Excellent

Excellent

Very good (Variable)

Excellent

Resistance to gas permeability

Excellent

Excellent

Poor

Excellent

Resistance to ageing due to stream

Excellent

Fair to good

Poor at temperatures over 150°C / 302°F

 

Compatibility with ketones

Excellent

Poor

Poor to fair

 

Compatibility with alcohols

Excellent (Variable)

Fair to good

Poor

 

 

Rubber at a glance:

  • Ethylene Propylene Diene Monomer (EPDM): Very flexible and similar to silicone, but with a lower temperature range.
  • Nitrile: While noted for its excellent resistance to oil, it’s resistance to DOT 3 brake fluids is less than satisfactory.
  • Silicone: In addition to providing the ideal material for masking caps and plugs, silicone’s chemical inertness makes it well suited for surgical and food-processing equipment.
  • TPR: High resistance to chemicals; combines the properties of rubber with the moulding capabilities of thermoplastics.

The masking process

Different materials are used to suit different purposes. For instance, caps and plugs made of low-density polyethylene (LDPE) are ideal for protecting applications during shipping because of its high-impact strength. It does offer excellent resistance to some chemicals, but it would not be suitable for the intensity of masking processes. When placed in high temperatures, it becomes soft, making it more susceptible to the effects of many chemicals. So what materials should your caps and plugs be in that instance?

Your aim is to protect holes, studs and electrical contact points, of course. Here’s a look at how materials common to masking caps and plugs stand up to the process you have in mind:

Application

TRP

Paper

EPDM

PVC

Silicone

Nylon 6.6

High-Temp Vinyl

Powder Coating

 

E coating

 

 

Anodising

 

 

Plating

 

 

Wet Paint

 

using caps and plugs

Using the correct material for your cap and plug helps provide a professional finish. By protecting important areas of fabricated metal from different chemicals during masking, you can give customers a product they’re happy with while minimising recalls.

Which caps and plugs? Quite a few can protect your application from the threat of chemicals in different situations:

General Purpose

 

Masking

Hose and Cable Protection

 

Automotive

 

Oil and Gas

  • LPG caps: These products helps prevent dangerous gas leaks
  • Gas cylinder valve caps: These products protects against ingress of dust and dirt and available with a vent flat to allow the safe release of gas
  • Clear adhesive discs: This range is resistant to petrol, oil and non-oxidisation acids
  • Protects petroleum, gas and water type valve flanges

Download free CADs and try before you buy

Download free CADs and request free samples, which are available for most of our solutions. It’s a great way to ensure you’ve chosen exactly what you need. If you’re not quite sure which product will work best, our experts are always happy to advise you.

Whatever your requirements, you can depend on fast despatch. Request your free samples or download free CADs now.

Questions?

Email us at sales@essentracomponents.co.uk or speak to one of our experts for further information on the ideal solution for your application 0345 528 0474.